86977-37-9

Basic information

• Product Name: 2-chloro-1,1,3-trimethoxycyclohexane
• CAS NO: 86977-37-9
• Molecular Weight: 208.685
• Mol File: 86977-37-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloro-1,1,3-trimethoxycyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-1,1,3-trimethoxycyclohexane(86977-37-9)
• EPA Substance Registry System: 2-chloro-1,1,3-trimethoxycyclohexane(86977-37-9)

Safety Data

• Hazardous Substances Data: 86977-37-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 86977-34-6 3,3-dichlorobicyclo<2.2.0>hexan-2-one 

Relevant articles and documents

SMALL RING COMPOUNDS-XLI. CYCLOBUTENE CYCLOADDITIONS; SYNTHESIS AND REACTIVITY IN THE BICYCLOHEXAN-2-ONE SERIES

Cyclobutene, prepared by base-induced elimination from tosyloxycyclobutane 19 undergoes cycloaddition with ethyl propiolate in the presence of AlCl3 to provide ethyl bicyclohex-2-ene-2-carboxylate 20.This cycloadduct at room temperature and in the presence of AlCl3 undergoes forbidden ring opening into ethyl cyclohexa-1,3-diene-2-carboxylate 21.The cycloaddition of cyclobutene with dichloroketene provides 3,3-dichlorobicyclohexan-2-one 24 and after reductive halogen removal the endo 3-chloro bicyclohexan-2-one 28 (the first study of this strained system).However, further dechlorination of 28 results in rearrangement and fragmentation reactions.