87010-93-3Relevant articles and documents
Synthesis of N-substituted derivatives of arylsulfonyl hydrazides and their investigation as additives for lubricating oils
Mamedov,Mamedova,Guseinov,Ladokhina,Fatalizade,Farzaliev
, p. 284 - 287 (2012/10/29)
The reaction between arylsulfonyl chlorides and hydrazine has been studied, and it has been found that in the presence of excess hydrazine, the bis-derivatives are produced in small amounts along with monoarylsulfonyl hydrazides. It has been revealed that the reaction of monosulfonyl hydrazides with alkyl bromides in the presence of a base results only in N-alkylation of the sulfamide nitrogen, although the reaction in the presence of HCl proceeds at the amine group with the formation of quaternary ammonium salts. A method for the preparation of sulfonyl hydrazides by oxidation of N-alkyl sulfamides in the presence of iodine has been developed. Some arylsulfonyl hydrazide derivatives have been examined as antioxidant, anti-rust, and antiwear additives. These sulfonyl hydrazides also exhibit a high bactericidal and fungicidal activity.