871-30-7Relevant articles and documents
METALLOMETHANE. VII. 199Hg-NMR-STUDIEN AN MERCURIMETHANEN CH4-n(HgX)n (X = Cl, Br, I UND CN)
Breitinger, Dietrich K.,Kress, Wolfram,Sendelbeck, Raymond,Ishiwada, Kenzoe
, p. 245 - 252 (2007/10/02)
199Hg NMR spectra of the partly newly prepared mercurimethanes CH4-n(HgX)n (1n4; X=Cl, Br, I and CN) have been measured.The chemical shifts δ(199Hg) indicate increasing deshielding of the mercury nuclei with increasing n and in the series I a fixed n are explained by changes in population and extension of the 6p orbitals of mercury.The variations of δ(199Hg) with n correlate with the course of excitation energies ΔE.The coupling constants 2J(199Hg-1H) decrease with growing trans influence of the ligands X.