87106-39-6

Basic information

• Product Name: 4(RS),8(S)-dimethyldecanal dimethyl acetal
• CAS NO: 87106-39-6
• Molecular Weight: 230.391
• Mol File: 87106-39-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4(RS),8(S)-dimethyldecanal dimethyl acetal(CAS DataBase Reference)
• NIST Chemistry Reference: 4(RS),8(S)-dimethyldecanal dimethyl acetal(87106-39-6)
• EPA Substance Registry System: 4(RS),8(S)-dimethyldecanal dimethyl acetal(87106-39-6)

Safety Data

• Hazardous Substances Data: 87106-39-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 86414-33-7 (6S,10S)-(+)-2,6,10-trimethyldodec-2-ene 
• 105485-71-0 ethyl 2-carbethoxy-4,8-dimethyldecanoate 
• 105485-68-5 ethyl 4,8-dimethyldecanoate 
• 105485-65-2 rhodinal 
• 28339-05-1 4,8-dimethyldecan-1-ol 
• 245118-38-1 (2R/S,6S)-(+)-2,6-dimethyl-1-octanol 
• 105500-65-0 1-bromo-2,6-dimethyloctane 
• 105485-66-3 2,6-dimethyl-1-octene 
• 75983-36-7 4(RS),8(S)-dimethyldecanal 
• 132723-88-7 (R)-6,6-dimethoxy-3-methylhexyl tosylate 
• 132723-90-1 (R)-(+)-6,6-dimethoxy-3-methylhexyl phenyl sulfone 
• 87158-18-7 methyl (R)-6,6-dimethoxy-3-methylhexanoate 
• 132723-87-6 (R)-(+)-6,6-dimethoxy-3-methyl-1-hexanol 

Relevant articles and documents

OZONOLYSIS OF ALKENES AND REACTIONS OF POLYFUNCTIONAL COMPOUNDS. XLVI. SYNTHESIS OF (4S,8S)-4,8-DIMETHYLDECANAL AND ITS DIMETHYL ACETAL

From accessible chiral structural blocks, namely, (R)-methyl-citronellate and (S)-2-methyl-1-butanol, (6S,10S)-2,6,10-trimethyl-2-dodecene was synthesized.The ozonolysis of this gave (4S,8S)-4,8-dimethyldecanal, one of the stereoisomers of the aggregation pheromone of the meal worms Tribolium confusium and T. castaneum, and its dimethyl acetal.

DIASTEREOTOPIC GROUP SELECTIVITY AT A PROSTEREOGENIC CARBON CENTER: SYNTHESIS OF (+/-)-SYN-4,8-DIMETHYLDECANAL

A group selective dealkylation reaction of a bridged ketal with trimethylsilyl iodide serves to control stereochemistry at carbon centers that are separated by five atoms.In combination with the iron/copper promoted fragmentation reaction of a hydroperoxi

SYNTHESIS OF ALL OF THE FOUR POSSIBLE STEREOISOMERS OF 4,8-DIMETHYLDECANAL, THE AGGREGATION PHEROMONE OF THE FLOUR BEETLES

The four stereoisomers of 4,8-dimethyldecanal were synthesized employing organometallic or electrolytic coupling reactions as the key step.The response of the red flour beetle, Tribolium castaneum, to the (4R,8R)-isomer was identical with that to the natural pheromone, while other isomers induced only very weak or no responses.The (4R,8R)-isomer is therefore the natural pheromone.