87109-17-9Relevant articles and documents
Synthesis of a caryophyllene isoprenologue, a potential diterpene natural product
Hinkley, Simon F.R.,Perry, Nigel B.,Weavers, Rex T.
, p. 3671 - 3680 (2007/10/03)
(-)-β-Caryophyllene has been converted into three stereoisomers of a new bicyclic compound that is structurally related to the known macrocyclic diterpene, flexibilene, in the same way β-caryophyllene is related to humulene. Key steps are selective cleava
STEREO-CONTROLLED SYNTHESIS OF γ,δ-UNSATURATED KETONES BY THE HORNER-WITTIG REACTION
Cornish, Christopher A.,Warren, Stuart
, p. 2603 - 2606 (2007/10/02)
E and Z isomers of γ,δ-unsaturated ketals may separately be prepared by the Horner-Wittig reaction between 5-diphenyl-phosphinoylpentan-2-one ethylene acetal (6) and aldehydes, esters, or ketones.