87118-43-2

Basic information

• Product Name: (4S,8R)-4,8-dimethyldecanal dimethylacetal
• Synonyms: (4S,8R)-4,8-dimethyldecanal dimethylacetal
• CAS NO: 87118-43-2
• Molecular Weight: 230.391
• Mol File: 87118-43-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4S,8R)-4,8-dimethyldecanal dimethylacetal(CAS DataBase Reference)
• NIST Chemistry Reference: (4S,8R)-4,8-dimethyldecanal dimethylacetal(87118-43-2)
• EPA Substance Registry System: (4S,8R)-4,8-dimethyldecanal dimethylacetal(87118-43-2)

Safety Data

• Hazardous Substances Data: 87118-43-2(Hazardous Substances Data)

Upstream product

• 15681-48-8 lithium dimethylcuprate 
• 108864-08-0 Toluene-4-sulfonic acid (2R,6S)-9,9-dimethoxy-2,6-dimethyl-nonyl ester 
• 97827-17-3 5-iodomethyl-2,2-dimethyl-1,3-dioxane 
• 105485-71-0 ethyl 2-carbethoxy-4,8-dimethyldecanoate 
• 105485-68-5 ethyl 4,8-dimethyldecanoate 
• 105485-65-2 rhodinal 
• 28339-05-1 4,8-dimethyldecan-1-ol 
• 245118-38-1 (2R/S,6S)-(+)-2,6-dimethyl-1-octanol 
• 105500-65-0 1-bromo-2,6-dimethyloctane 
• 105485-66-3 2,6-dimethyl-1-octene 
• 67-56-1 methanol 
• 75983-36-7 4(RS),8(S)-dimethyldecanal 
• 132723-88-7 (R)-6,6-dimethoxy-3-methylhexyl tosylate 
• 132723-90-1 (R)-(+)-6,6-dimethoxy-3-methylhexyl phenyl sulfone 

Relevant articles and documents

Pheromone Synthesis, CXXX. Synthesis of (4S,8S)- and (4S,8R)-4,8-Dimethyldecanal, the Stereoisomers of the Aggregation Pheromone of Tribolium castaneum

(4S,8S)- and (4S,8R)-4,8-Dimethyldecanal (1) were synthesized by starting from (R)-citronellic acid (2a), methyl (S)-3-hydroxyy-2-methylpropanoate (3a), and (S)-2-methyl-1-butanol (4a).

DIASTEREOTOPIC GROUP SELECTIVITY AT A PROSTEREOGENIC CARBON CENTER: SYNTHESIS OF (+/-)-SYN-4,8-DIMETHYLDECANAL

A group selective dealkylation reaction of a bridged ketal with trimethylsilyl iodide serves to control stereochemistry at carbon centers that are separated by five atoms.In combination with the iron/copper promoted fragmentation reaction of a hydroperoxi