87121-18-4

Basic information

• Product Name: 3-(2,2-Bis-trimethylsilanyloxy-vinyl)-2,2-diphenyl-cyclobutanone
• Synonyms: 3-(2,2-Bis-trimethylsilanyloxy-vinyl)-2,2-diphenyl-cyclobutanone
• CAS NO: 87121-18-4
• Molecular Weight: 424.687
• Mol File: 87121-18-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(2,2-Bis-trimethylsilanyloxy-vinyl)-2,2-diphenyl-cyclobutanone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2,2-Bis-trimethylsilanyloxy-vinyl)-2,2-diphenyl-cyclobutanone(87121-18-4)
• EPA Substance Registry System: 3-(2,2-Bis-trimethylsilanyloxy-vinyl)-2,2-diphenyl-cyclobutanone(87121-18-4)

Safety Data

• Hazardous Substances Data: 87121-18-4(Hazardous Substances Data)

Upstream product

• 87121-06-0 1,1-bis(trimethylsilyloxy)-buta-1,3-diene 
• 525-06-4 diphenyl ketene 
• 88239-44-5 (crotonoyloxy)trimethylsilane 

Downstream Products

• 87121-15-1 2-(2,2-diphenyl-3-oxocyclobutyl)acetanilide 
• 87121-19-5 (3-Oxo-2,2-diphenyl-cyclobutyl)-acetic acid 

Relevant articles and documents

Halogenated Ketenes. 37. The Synthesis of Pyranones Utilizing the (4 + 2) Cycloaddition of Ketenes and Siloxy Dienes

The reaction of diphenyl-, dichloro-, and chloroketenes with several siloxy dienes results in (4 + 2) and/or (2 + 2) cycloaddition products depending primarily on substitution in the diene.The (4 + 2) cycloaddition products are easily hydrolyzed to pyranones.These results are discussed in terms of a dipolar intermediate.