871217-81-1Relevant articles and documents
Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step
Gong, Yuanzheng,Yang, Chun,Ji, Hongwei,Chen, Chuncheng,Ma, Wanhong,Zhao, Jincai
supporting information, p. 2048 - 2051 (2017/08/23)
In aqueous TiO2 photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7–0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced hvb + can be the rate-determining step.
Deuterium NMR spectroscopy is a versatile and economical tool for monitoring reaction kinetics in ionic liquids
Durazo, Armando,Abu-Omar, Mahdi M.
, p. 66 - 67 (2007/10/03)
Time-resolved 2H NMR spectroscopy is used to monitor the progress of and gain kinetic information for a variety of reactions in different ionic media.