87124-96-7

Basic information

• Product Name: 1-m-tolyl-propane-1,2-dione-2-oxime
• Synonyms: 1-m-tolyl-propane-1,2-dione-2-oxime
• CAS NO: 87124-96-7
• Molecular Weight: 177.203
• Mol File: 87124-96-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-m-tolyl-propane-1,2-dione-2-oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-m-tolyl-propane-1,2-dione-2-oxime(87124-96-7)
• EPA Substance Registry System: 1-m-tolyl-propane-1,2-dione-2-oxime(87124-96-7)

Safety Data

• Hazardous Substances Data: 87124-96-7(Hazardous Substances Data)

Upstream product

• 51772-30-6 3'-Methylpropiophenone 
• 544-16-1 n-Butyl nitrite 

Relevant articles and documents

Visible-Light-Induced Transition-Metal-Free Nitrogen-Centered Radical Strategy for the Synthesis of 2-Acylated 9 H-Pyrrolo[1,2- a]indoles

A convenient and efficient visible-light-induced tandem acylation/cyclization of N-propargylindoles with aryl- or alkyl-substituted acyl oxime esters for the synthesis of 2-acyl-substituted 9H-pyrrolo[1,2-a]indoles under transition-metal-free conditions, which proceeds via nitrogen-centered radical-mediated cleavage of the C-C σ-bond in acyl oxime esters, is established. The aryl or alkyl acyl radicals, which come from acyl oxime esters, attack the C-C triple bonds in N-propargylindoles and then go through intramolecular cyclization/isomerization.