87144-81-8Relevant articles and documents
A DERIVATIVE OF AZEPINE AND ITS APPLICATION AS A SPECIFIC OPTICAL RESOLUTION AGENT
Fernandez, Franco,Perez, Cristina
, p. 2411 - 2417 (2007/10/02)
The synthesis of (-)-(2S,trans)-perhydro-2-isopropyl-5-methyl-azepin-1-amine (1) and its use as a specific optical resolution agent of ketones is described.A method for the resolution of ketones and its application to three ketones is described.This method also involves the synthesis and separation of the pairs of hydrazones diastereomers followed by removal of hydrazines by hydrolysis to give the individual enantiomers of II, III and IV with high chiral purities.
Successive Beckmann Rearrangement-Alkylation Sequence by Organoaluminium Reagnts. A Simple Route to dl-Pumiliotoxin C
Hattori, Kazunobu,Matsumura, Yasushi,Miyazaki, Tohru,Maruoka, Keiji,Yamamoto, Hisashi
, p. 7368 - 7370 (2007/10/02)
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