87188-51-0

Basic information

• Product Name: TERT-BUTYL 4-VINYLPHENYL CARBONATE
• Synonyms: 1,1-dimethylethyl4-ethenylphenylcarbonate;4-boc-styrene;c-1566;carbonicacid,1,1-dimethylethyl4-ethenylphenylester;p-tert-butoxycarbonyloxystyrenemonomer;tbsm;p-tert-Butoxycarbonyloxystyrene;TERT-BUTYL 4-VINYLPHENYL CARBONATE
• CAS NO: 87188-51-0
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.26
• Mol File: 87188-51-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 27-29 °C(lit.)
• Boiling Point: 187 °C(lit.)
• Flash Point: >230 °F
• Appearance: WHITE TO OFF-WHITE POWDER, CRYSTALS,CRYSTALLINE SOLID AND/OR CHUNKS
• Density: 1.1101 (rough estimate)
• Vapor Pressure: 0.000665mmHg at 25°C
• Refractive Index: 1.5090 (estimate)
• CAS DataBase Reference: TERT-BUTYL 4-VINYLPHENYL CARBONATE(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-BUTYL 4-VINYLPHENYL CARBONATE(87188-51-0)
• EPA Substance Registry System: TERT-BUTYL 4-VINYLPHENYL CARBONATE(87188-51-0)

Safety Data

• WGK Germany: 2
• RTECS: FG0460000
• Hazardous Substances Data: 87188-51-0(Hazardous Substances Data)

Usage

Hazard

Moderately toxic by skin contact. A mild skin irritant.

InChI:InChI=1/C13H16O3/c1-5-10-6-8-11(9-7-10)15-12(14)16-13(2,3)4/h5-9H,1H2,2-4H3

Upstream product

• 2628-16-2 p-acetoxystyrene 
• 24424-99-5 di-tert-butyl dicarbonate 
• 32503-27-8 tetra(n-butyl)ammonium hydrogensulfate 
• 7400-08-0 para-coumaric acid 

Relevant articles and documents

METHOD OF PRODUCING HYDROXYSTYRENE DERIVATIVE

PROBLEM TO BE SOLVED: To provide a method of producing hydroxystyrene compounds and their derivatives, simply in a high yield, by using relatively inexpensive and easily removable agents and relatively mild conditions. SOLUTION: A method of producing hydroxystyrene compounds comprises decarboxylating a hydroxycinnamic acid compound in a solvent containing at least one solvent having an amide bond in the presence of water and/or hydroxy-containing compound. A method of producing hydroxystyrene derivatives comprises reacting the hydroxystyrene compound with an acylating agent and/or a carbonic esterification agent. COPYRIGHT: (C)2015,JPOandINPIT

Process for preparing substituted styrenes

Substituted styrenes are synthesized by a simple, low temperature technique. A protected phenol styrene is reacted with an acid anhydride, dicarbonate, a halogen substituted alkyl, or an acid chloride in the presence of base to form a carbonyl substituted styrene. Unexpected yield decrease due to distillation is avoided because the product is sufficiently pure to be used without such distillation.

Process for preparation of alkoxycarbonyloxystyrene

The present invention provides a process for the preparation of alkoxycarbonyloxystyrene comprising reacting acyloxystyrene with a strong base to yield a phenolate to which is added an alkoxycarbonylating agent in an organic solvent and a phase transfer c