871894-87-0

Basic information

• Product Name: N-(4-hydroxy-3,5,6-trinitrophenyl)acetamide
• Synonyms: N-(4-hydroxy-3,5,6-trinitrophenyl)acetamide
• CAS NO: 871894-87-0
• Molecular Weight: 286.158
• Mol File: 871894-87-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-hydroxy-3,5,6-trinitrophenyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-hydroxy-3,5,6-trinitrophenyl)acetamide(871894-87-0)
• EPA Substance Registry System: N-(4-hydroxy-3,5,6-trinitrophenyl)acetamide(871894-87-0)

Safety Data

• Hazardous Substances Data: 871894-87-0(Hazardous Substances Data)

Upstream product

• 123-30-8 4-amino-phenol 
• 871878-62-5 acetic acid-(4-hydroxy-2,5-dinitro-anilide) 
• 7403-75-0 N-(4-hydroxy-2-nitrophenyl)-acetamide 
• 7697-37-2 nitric acid 
• 64-19-7 acetic acid 
• 7664-93-9 sulfuric acid 
• 2243-69-8 4-acetamido-3-nitrophenyl acetate 
• 2623-33-8 4-acetoxyacetanilide 

Downstream Products

• 91144-94-4 4-hydroxy-2,3,5-trinitro-benzenediazonium-betaine 

Relevant articles and documents

Synthesis and Energetic Properties of 4-Diazo-2,6-dinitrophenol and 6-Diazo-3-hydroxy-2,4-dinitrophenol

4-Amino-3,5-dinitroaniline (3) was synthesized by fluorine/amine exchange of 4-fluoro-3,5-dinitroaniline in ethanol. 4-Diazo-2,6-dinitrophenol (Iso-DDNP, 4) was obtained after nitration in HNO3 (100%) and acetic anhydrid. 4-Amino-2,3,5-trinitrophenol (7) was obtained by nitration of N-(4-acetoxyphenyl)acetamide and deprotection of the amine. Further nitration resulted in 6-diazo-3-hydroxy-2,4-dinitrophenol (8). The thermal stability and sensitivity of 4 and 8 toward impact and friction was compared to commercially used DDNP (2-diazo-4,6-dinitrophenol). All target compounds were characterized by single-crystal X-ray diffraction, NMR and elemental analysis and DSC. The sensitivities were determined by BAM methods (drophammer and friction tester). The heats of formation were calculated by using CBS-4M electronic enthalpies and the atomization method. Various detonation parameters such as detonation velocity and pressure were computed by using the EXPLO5 computer code V6.01. The very sensitive diazophenol derivatives diazo-2,6-dinitrophenol and 6-diazo-3-hydroxy-2,4-dinitrophenol could be synthesized by nitration reactions. They are promising alternatives to the commercially used sensitizer DDNP (2-diazo-4,6-dinitrophenol).