871897-28-8Relevant articles and documents
A brand-new Pd-mediated generation of benzyne and its [2+2+2] cycloaddition: δ-carbon elimination and concomitant decarboxylation
Kim, Hoo Sook,Gowrisankar, Saravanan,Kim, Eun Sun,Kim, Jae Nyoung
scheme or table, p. 6569 - 6572 (2009/04/05)
We found a brand-new method for the generation of aryne from methyl 2-bromobenzoates via the Pd-mediated concomitant δ-carbon elimination and decarboxylation. The generated arynes underwent Pd-mediated [2+2+2] cycloaddition to give triphenylenes.