872041-27-5

Basic information

• Product Name: (HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*GaCl₄^(1-)=(HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)(GaCl₄)
• CAS NO: 872041-27-5
• Molecular Weight: 838.064
• Mol File: 872041-27-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*GaCl₄^(1-)=(HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)(GaCl₄)(CAS DataBase Reference)
• NIST Chemistry Reference: (HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*GaCl₄^(1-)=(HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)(GaCl₄)(872041-27-5)
• EPA Substance Registry System: (HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)⁽¹⁺⁾*GaCl₄^(1-)=(HN(C₆H₄)2AsP(C₆H₅)2CH₂P(C₆H₅)2)(GaCl₄)(872041-27-5)

Safety Data

• Hazardous Substances Data: 872041-27-5(Hazardous Substances Data)

Upstream product

• 578-94-9 adamsite 
• 13450-90-3 Gallium trichloride 
• 2071-20-7 bis-diphenylphosphinomethane 

Relevant articles and documents

Arsinophosphonium cations from arsenium-phosphine and -bisphosphine coordination chemistry

A new 14π-electron tricyclic organoarsenium cation (5- hydrophenarsazinium, AN, C12H9AsN+) has been prepared in situ and used as a Lewis acceptor with trimethylphosphine, triphenylphosphine, bis(diphenylphosphino)methane (dppm), bis(dimethylphosphino) methane (dmpm), and 1,4-bis(diphenylphosphino)benzene (dppb) ligands. Solid-state structures and spectroscopic characterization data are reported for complexes of the general formula [AN-PMe3]+, [AN-PPh 3]+, [AN-dppm]+, [AN-dppm-AN]2+, [AN-dmpm-AN]2+, and [AN-dppb-AN]2+ as tetrachlorogallate salts. Depending on reaction stoichiometry, dppm forms adducts at one or both of the donor sites. Structural comparisons with analogous complexes of phosphenium cations provide interesting similarities and differences.