87243-12-7

Basic information

• Product Name: 4⁽⁵⁾-Nitro-5⁽⁴⁾-phenylaminoimidazole
• Synonyms: 4⁽⁵⁾-Nitro-5⁽⁴⁾-phenylaminoimidazole
• CAS NO: 87243-12-7
• Molecular Weight: 204.188
• Mol File: 87243-12-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4⁽⁵⁾-Nitro-5⁽⁴⁾-phenylaminoimidazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4⁽⁵⁾-Nitro-5⁽⁴⁾-phenylaminoimidazole(87243-12-7)
• EPA Substance Registry System: 4⁽⁵⁾-Nitro-5⁽⁴⁾-phenylaminoimidazole(87243-12-7)

Safety Data

• Hazardous Substances Data: 87243-12-7(Hazardous Substances Data)

Upstream product

• 41384-83-2 1-phenyl-4-nitro-1H-imidazole 
• 6963-65-1 5-bromo-4-nitro-1H-imidazole 
• 62-53-3 aniline 
• 19183-14-3 4,5-dinitro-1H-imidazole 
• 152483-39-1 5-amino-4-nitro-1-phenylimidazole 

Downstream Products

• 95862-41-2 (3-methyl-5-nitro-3H-imidazol-4-yl)-phenyl-amine 

Relevant articles and documents

REACTIONS OF 4,5-DINITROIMIDAZOLE AND 4(5)-NITROIMIDAZOLE-5(4)-SULFONIC ACID WITH NUCLEOPHILES

The reactions of 4,5-dinitroimidazole and 5(4)-nitroimidazole-4(5)-sulfonic acid with nucleophilic agents were studied.Mercapto-, alkoxy-, and aminonitroimidazoles were synthesized.In the reaction of dinitroimidazole with sodium alkoxides 5(4)-nitroimidazole was obtained in addition to alkoxynitroimidazoles.It is shown that in the formation of salts of the starting imidazoles with bases nucleophilic-substitution reactions take place only with "soft" reagents.

RING TRANSFORMATION REACTIONS IN 4-NITROIMIDAZOLES FOLLOWING AN ATTACK OF NUCLEOPHILES

It was proved that 4-nitroimidazoles substituted at the nitrogen atom 1 with electron acceptor groups (aryl, arenesulfonyl, nitro) in reactions with some nucleophiles yield the products of ordinary or degenerated imidazole ring transformation (oxadiazoles, triazoles, imidazoles).