87275-35-2

Basic information

• Product Name: 2-(α-bromocyclohexoxy)-1-acetoxybenzene
• CAS NO: 87275-35-2
• Molecular Weight: 313.191
• Mol File: 87275-35-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(α-bromocyclohexoxy)-1-acetoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(α-bromocyclohexoxy)-1-acetoxybenzene(87275-35-2)
• EPA Substance Registry System: 2-(α-bromocyclohexoxy)-1-acetoxybenzene(87275-35-2)

Safety Data

• Hazardous Substances Data: 87275-35-2(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 182-55-8 spiro[benzo[d][1,3]dioxole-2,1'-cyclohexane] 

Relevant articles and documents

Studies on the Synthesis of Heterocyclic Compounds. XI. Cleavage of 1,3-Benzodioxoles by Magnesium Bromide-Acetic Anhydride

The cleavage reaction of some 1,3-benzodioxole derivatives with magnesium bromide and acetic anhydride has been studied.The reactions have been carried out in acetonitrile solution at room temperature.In all of the 1,3-benzodioxoles studied, the opening of the heterocyclic ring with formation of bromides, alkenes and their corresponding products of hydrolysis have been observed.The competitive electrophilic substitution on the benzene ring was very limited and was insignificant when a large excess of the cleavage reagent was used.The structures of newly prepared compounds have been determined by elemental analysis, spectroscopic data and comparison with authentic samples.