873685-06-4

Basic information

• Product Name: Benzenemethanamine, N-(2-bromophenyl)-a-methyl-, (aR)-
• Synonyms: Benzenemethanamine, N-(2-bromophenyl)-a-methyl-, (aR)-
• CAS NO: 873685-06-4
• Molecular Formula: C₁₄H₁₄BrN
• Molecular Weight: 276.176
• Mol File: 873685-06-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 354.5°C at 760 mmHg
• Flash Point: 168.2°C
• Appearance: /
• Density: 1.36g/cm³
• Vapor Pressure: 3.34E-05mmHg at 25°C
• Refractive Index: 1.634
• CAS DataBase Reference: Benzenemethanamine, N-(2-bromophenyl)-a-methyl-, (aR)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-(2-bromophenyl)-a-methyl-, (aR)-(873685-06-4)
• EPA Substance Registry System: Benzenemethanamine, N-(2-bromophenyl)-a-methyl-, (aR)-(873685-06-4)

Safety Data

• Hazardous Substances Data: 873685-06-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H14BrN/c1-11(12-7-3-2-4-8-12)16-14-10-6-5-9-13(14)15/h2-11,16H,1H3/t11-/m1/s1

Upstream product

• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 583-53-9 2,3-dibromobenzene 

Downstream Products

• 873685-07-5 N,N'-bis[(R)-1-phenyl-ethyl]benzene-1,2-diamine 
• 779-54-4 (R)-phenyl-(1-phenylethyl)amine 
• 873685-08-6 N,N'-bis-(R)-α-methylbenzyl-benzimidazolium silver(I) chloride 

Relevant articles and documents

Enantioselective copper catalysed 1,4-conjugate addition reactions using chiral N-heterocyclic carbenes

The preparation of a variety of chiral N-heterocyclic carbene (NHC) precursors is described. The relative merits of imidazolinium salts and silver carbenes as NHC precursors are discussed with respect to their synthesis, stability and performance in the copper catalysed conjugate addition of dialkyl zinc reagents to a variety of Michael acceptors. Enantioselectivities of up to 93% were achieved using as little as 4% of chiral ligand.