87384-00-7

Basic information

• Product Name: Dimethyl isopropylidenesuccinate, tech.
• Synonyms: Dimethyl isopropylidenesuccinate, tech.;Dimethylisopropylidenesuccinate
• CAS NO: 87384-00-7
• Molecular Formula: C9H14O4
• Molecular Weight: 186.20506
• Mol File: 87384-00-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 240°Cat760mmHg
• Flash Point: 111°C
• Appearance: /
• Density: 1.05g/cm³
• Vapor Pressure: 0.0388mmHg at 25°C
• Refractive Index: 1.443
• CAS DataBase Reference: Dimethyl isopropylidenesuccinate, tech.(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl isopropylidenesuccinate, tech.(87384-00-7)
• EPA Substance Registry System: Dimethyl isopropylidenesuccinate, tech.(87384-00-7)

Safety Data

• Hazardous Substances Data: 87384-00-7(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 9247, 1994 DOI: 10.1016/0040-4039(94)88479-X

InChI:InChI=1/C9H14O4/c1-6(2)7(9(11)13-4)5-8(10)12-3/h5H2,1-4H3

Upstream product

• 594-16-1 2,2-dibromopropane 
• 624-48-6 dimethyl cis-but-2-ene-1,4-dioate 
• 594-20-7 2,2-dichloropropane 
• 624-49-7 dimethylfumarate 
• 108-20-3 di-isopropyl ether 

Relevant articles and documents

Photochemical addition of cyclic ethers/acetals to olefins using tBuOOtBu: Synthesis of masked ketones/aldehydes and diols

A fast photochemical C–C bond formation between cyclic ethers/acetals and olefins using di-tert-butyl peroxide (DTBP) was developed. This method provides easy access to 2-substituted cyclic ethers, and 2- or 4-substituted cyclic acetals. Acyl/formyl groups or diols can be obtained by the hydrolysis of the 2- or 4-substituted cyclic acetals, respectively. The reactions proceeded at room temperature and gave the expected products in good to excellent yields; efficient reactions were completed within 0.5 h at room temperature in >95% yield.