87432-45-9

Basic information

• Product Name: 5'-O-(tert-butyldiphenylsilyl)-2'-O-tosyladenosine
• Synonyms: 5'-O-(tert-butyldiphenylsilyl)-2'-O-tosyladenosine
• CAS NO: 87432-45-9
• Molecular Weight: 659.838
• Mol File: 87432-45-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5'-O-(tert-butyldiphenylsilyl)-2'-O-tosyladenosine(CAS DataBase Reference)
• NIST Chemistry Reference: 5'-O-(tert-butyldiphenylsilyl)-2'-O-tosyladenosine(87432-45-9)
• EPA Substance Registry System: 5'-O-(tert-butyldiphenylsilyl)-2'-O-tosyladenosine(87432-45-9)

Safety Data

• Hazardous Substances Data: 87432-45-9(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 42776-78-3 2'-O-tosyladenosine 

Downstream Products

• 87432-46-0 9-(5-O-TPS-2-deoxy-β-D-threo-pentofuranosyl)adenine 
• 66224-66-6 adenine 

Relevant articles and documents

Deoxygenative [1,2]-hydride shift rearrangements in nucleoside and sugar chemistry: Analogy with the [1,2]-electron shift in the deoxygenation of ribonucleotides by ribonucleotide reductases

(Chemical Equation Presented) A variant of the semipinacol rearrangement that was observed in our laboratory has been applied to the synthesis of several furanose and pyranose derivatives. The process consists of an "orchestrated" [1,2]-hydride shift with