874384-01-7

Basic information

• Product Name: 4-Pentenoic acid, 2-[bis(phenylmethyl)amino]-, phenylmethyl ester, (2S)-
• CAS NO: 874384-01-7
• Molecular Formula: C26H27NO2
• Molecular Weight: 385.506
• Mol File: 874384-01-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-Pentenoic acid, 2-[bis(phenylmethyl)amino]-, phenylmethyl ester, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenoic acid, 2-[bis(phenylmethyl)amino]-, phenylmethyl ester, (2S)-(874384-01-7)
• EPA Substance Registry System: 4-Pentenoic acid, 2-[bis(phenylmethyl)amino]-, phenylmethyl ester, (2S)-(874384-01-7)

Safety Data

• Hazardous Substances Data: 874384-01-7(Hazardous Substances Data)

Upstream product

• 16338-48-0 L-allylglycine 
• 100-39-0 benzyl bromide 

Downstream Products

• 874384-02-8 (S)-2-(dibenzylamino)-6-oxohexanoic acid benzyl ester 

Relevant articles and documents

Diastereoselective and Branched-Aldehyde-Selective Tandem Hydroformylation-Hemiaminal Formation: Synthesis of Functionalized Piperidines and Amino Alcohols

Starting from readily available allylglycine, a tandem hydroformylation-hemiaminal formation reaction has been developed for the synthesis of chiral functionalized piperidines, with very good diastereoselectivity and branched regioselectivity using Rh/(S,

Manganese Catalyzed Hydrogenation of Enantiomerically Pure Esters

A manganese-catalyzed hydrogenation of esters has been accomplished with TONs up to 1000, using cheap, environmentally benign, potassium carbonate and simple alcohols as activator and solvent, respectively. The weakly basic conditions lead to good functional group tolerance and enable the hydrogenation of enantiomerically enriched α-chiral esters with essentially no loss of stereochemical integrity.