87446-53-5

Basic information

• Product Name: S,S-diphenyl-N-(trifluoroacetyl)sulfilimine
• Synonyms: S,S-diphenyl-N-(trifluoroacetyl)sulfilimine
• CAS NO: 87446-53-5
• Molecular Weight: 297.301
• Mol File: 87446-53-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: S,S-diphenyl-N-(trifluoroacetyl)sulfilimine(CAS DataBase Reference)
• NIST Chemistry Reference: S,S-diphenyl-N-(trifluoroacetyl)sulfilimine(87446-53-5)
• EPA Substance Registry System: S,S-diphenyl-N-(trifluoroacetyl)sulfilimine(87446-53-5)

Safety Data

• Hazardous Substances Data: 87446-53-5(Hazardous Substances Data)

Upstream product

• 36744-90-8 S,S-Diphenylsulfilimine 
• 407-25-0 trifluoroacetic anhydride 
• 354-38-1 2,2,2-trifluoroacetamide 
• 139-66-2 diphenyl sulfide 

Downstream Products

• 54287-71-7 phenyl 2-(phenylamino)phenyl sulfide 
• 36744-90-8 S,S-Diphenylsulfilimine 
• 87446-50-2 5,5-Diphenyl-2-trifluoromethyl-oxazol-4-one 
• 87446-54-6 2-hydroxy-2-(trifluoromethyl)-5,5-diphenyl-4-oxazolidinone 

Relevant articles and documents

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.

Reactions of Ketenes with Sulfilimines. Synthetic Routes to Oxazolinones and Indolinones

The reactions of diphenylketene and tert-butylcyanoketene with several sulfilimines were investigated. 5,5-Diphenyl-2-oxazolin-4-ones were produced from N-acylsulfilimines and diphenylketene while a 2-indolinone was obtained from N-arylsulfilimine and the same ketene. tert-Butylcyanoketene afforded either simple substituted or ortho-rearranged amides when S,S-dimethylsulfilimines were used as substrates.The structure of 2,5,5-triphenyloxazolidin-4-one (7b) was confirmed by single-crystal X-ray examination.Possible mechanistic pathways which account for all observed products are discussed.