87556-01-2

Basic information

• Product Name: 8,21-ditosyl-8,21,27,28,29,30-hexaazapentacyclo<21.3.1.1^2,6.1^10,14.1^15,19>triaconto-1(27),2,4,6(30),10,12,14(29),15,17,19,(28),23,25-dodecaene
• Synonyms: 8,21-ditosyl-8,21,27,28,29,30-hexaazapentacyclo<21.3.1.1^2,6.1^10,14.1^15,19>triaconto-1(27),2,4,6(30),10,12,14(29),15,17,19,(28),23,25-dodecaene
• CAS NO: 87556-01-2
• Molecular Weight: 702.858
• Mol File: 87556-01-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 8,21-ditosyl-8,21,27,28,29,30-hexaazapentacyclo<21.3.1.1^2,6.1^10,14.1^15,19>triaconto-1(27),2,4,6(30),10,12,14(29),15,17,19,(28),23,25-dodecaene(CAS DataBase Reference)
• NIST Chemistry Reference: 8,21-ditosyl-8,21,27,28,29,30-hexaazapentacyclo<21.3.1.1^2,6.1^10,14.1^15,19>triaconto-1(27),2,4,6(30),10,12,14(29),15,17,19,(28),23,25-dodecaene(87556-01-2)
• EPA Substance Registry System: 8,21-ditosyl-8,21,27,28,29,30-hexaazapentacyclo<21.3.1.1^2,6.1^10,14.1^15,19>triaconto-1(27),2,4,6(30),10,12,14(29),15,17,19,(28),23,25-dodecaene(87556-01-2)

Safety Data

• Hazardous Substances Data: 87556-01-2(Hazardous Substances Data)

Upstream product

• 96517-97-4 6,6'-bis-(bromomethyl)-2,2'-bipyridine 
• 4411-80-7 6,6'-dimethyl-2,2'-bipyridine 
• 98-59-9 p-toluenesulfonyl chloride 
• 117053-65-3 6,6'-Bis(aminomethyl)-2,2'-bipyridine 
• 117053-66-4 N,N'-Ditosyl-6,6'-bis(aminomethyl)-2,2'-bipyridin 
• 74065-64-8 6,6'-di(chloromethyl)-2,2'-bipyridine 
• 18522-92-4 sodium p-toluenesulfonamide 

Relevant articles and documents

Photoactive Cryptands Synthesis of the Sodium Cryptates of Macrobicyclic Ligands Containing Bipyridine and Phenanthroline Groups

The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, i.e. of 1 2 3 4 and 5, have been prepared. 1, 2, 4 and 5 have been obtained in high yield by condensation of bis(bromomethyl)bipyridine 6 or -phenanthroline 9 with the corresponding macrocyclic diamines in presence of Na2CO3.Direct access to the NaBr complexes of the symmetrical cryptands 1 and 3 was achieved by a one-step macrobicyclisation procedure.The metal-ion complexes of ligands 1-5 have the attractive feature of combining the cation inclusion nature of cryptates with the photoactivity of bipyridine and phenanthroline groups; they may thus be expected to possess a variety of interesting physical and chemical properties.

Podands, Coronands and Cryptands as New Complex-Ligands in Photoelectron Transfer Reactions. Synthesis and Photophysical Studies

Podands, coronands and cryptands containing 2,2'-bipyridine-units were synthesized.These compounds can be used as ligands in Ru(II)-polypyridinecomplexes.This new route principally allows the preparation of tris-heteroleptic complexes using the appropriate cryptands.Ru(II)-polypyridines RuL3(2+) (e.g.Ru(bpy)3(2+)) are interesting as sensitizers in photochemical water cleavage.Compared to Ru(bpy)3(2+), the photoanationrate should be reduced in the Ru(cryp)(2+) complex. - Keywords: Podands, Coronands, Cryptands, Photosensitizer, Photoanation

A VERSATILE ONE-POT SYNTHESIS OF SYMMETRICAL N-TOSYLAZAMACROCYCLES

A variety of title compounds (azacrown ethers, pyridino-azacrown analogues and azacyclophanes) have been synthesized in moderate to good yield by coupling appropriate bis(halomethyl) or bis(tosylate ester) precursors with tosylamide monosodium salt.A revised mechanism is proposed.