875766-02-2

Basic information

• Product Name: cis-[Pt(II)(pentafluorophenyl)2(1,3-bis(diphenylphosphino)propane)]
• CAS NO: 875766-02-2
• Molecular Weight: 941.647
• Mol File: 875766-02-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-[Pt(II)(pentafluorophenyl)2(1,3-bis(diphenylphosphino)propane)](CAS DataBase Reference)
• NIST Chemistry Reference: cis-[Pt(II)(pentafluorophenyl)2(1,3-bis(diphenylphosphino)propane)](875766-02-2)
• EPA Substance Registry System: cis-[Pt(II)(pentafluorophenyl)2(1,3-bis(diphenylphosphino)propane)](875766-02-2)

Safety Data

• Hazardous Substances Data: 875766-02-2(Hazardous Substances Data)

Upstream product

• 68558-86-1 thallium(I) pentafluorobenzoate 
• 868157-81-7 [dichloroplatinum(II)( μ-1,3-bis(diphenylphosphano)propane)]*CH2Cl2 

Relevant articles and documents

The synthesis by decarboxylation reactions and crystal structures of 1,n-bis(diphenylphosphino)alkane(pentafluorophenyl)-platinum(II) complexes

Decarboxylation reactions between the complexes cis-[PtCl2L] (L = 1,n-bis(diphenylphosphino)-ethane (n = 2, dppe), -propane (n = 3, dppp) or -butane (n = 4, dppb)) and thallium(I) pentafluorobenzoate in pyridine give cis-[PtCl(C6F5)L] and cis-[Pt(C6F 5)2L] complexes in high yields with short reaction times. X-ray crystal structures of cis-[PtCl(C6F5)(dppe)] ·0.5 C5H5N, cis-[PtCl(C6F 5)(dppp)], cis-[PtCl(C6F5)(dppb)]·C 3H6O. cis-[Pt(C6F5)2L] (L = dppe, dppp and dppb) and the reactants cis-[PtCl2(dppp)] (as a CH2Cl2 solvate) and cis-[PtCl2(dppb)] show monomeric structures with chelating diphosphine ligands in all cases rather than dimers with bridging diphosphines. 31P NMR data are consistent with these structures in solution.