875877-83-1

Basic information

• Product Name: Silane, [[1-(4-chlorophenyl)-3-phenyl-2-propynyl]oxy]trimethyl-
• CAS NO: 875877-83-1
• Molecular Formula: C18H19ClOSi
• Molecular Weight: 314.887
• Mol File: 875877-83-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, [[1-(4-chlorophenyl)-3-phenyl-2-propynyl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[1-(4-chlorophenyl)-3-phenyl-2-propynyl]oxy]trimethyl-(875877-83-1)
• EPA Substance Registry System: Silane, [[1-(4-chlorophenyl)-3-phenyl-2-propynyl]oxy]trimethyl-(875877-83-1)

Safety Data

• Hazardous Substances Data: 875877-83-1(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 104-88-1 4-chlorobenzaldehyde 
• 75-77-4 chloro-trimethyl-silane 
• 102990-14-7 1-(4-chlorophenyl)-3-phenylprop-2-yn-1-ol 

Downstream Products

• 72826-55-2 (2Z)-1-(4-chlorophenyl)-3-phenylprop-2-en-1-one 
• 22966-22-9 (E)-1-(4-chlorophenyl)-3-phenyl-2-propen-1-one 
• 956-02-5 4'-chlorochalcone 

Relevant articles and documents

Catalytic deprotonative functionalization of propargyl silyl ethers with imines

A metal-free, catalytic C-H functionalization of propargyl silyl ethers with imines using the phosphazene base (t-Bu-P4 base) provides structurally defined multisubstituted pyrroles in modest to excellent yields under mild conditions. A one-pot, three-component reaction using silylated acetylenes, aldehydes, and imines is also presented.

Synthesis of β-branched Morita-Baylis-Hillman-type adducts from 1,3-diaryl-2-propynyl trimethylsilyl ethers and aldehydes catalyzed by potassium tert-butoxide

1,3-Diaryl-2-propynyl trimethylsilyl ethers were easy to isomerize into the corresponding siloxyallenes using a catalytic amount of potassium tert-butoxide under very mild conditions. The siloxyallenes reacted in situ with various aldehydes to afford Z-selective β-branched Morita-Baylis-Hillman-type adducts in a one-pot reaction after acid treatment.