87591-37-5Relevant articles and documents
Esterase catalyzed regioselective hydrolyses of acetylated monosaccharides
Tomic, Srdanka,Ljevakovic, Durjica,Tomasic, Jelka
, p. 10977 - 10986 (2007/10/02)
Deacylations of fully acylated D-glucopyranoses, methyl D-glucopyranosides, 2-acetamido-2-deoxy-D-glucopyranoses glucopyranoses and methyl 2-acetamido-2-deoxy-D-glucopyranosides catalyzed by rabbit serum or the esterase isolated from rabbit serum were investigated. Depending on the structure of the acyl protecting group a high degree of regioselectivity is observed. Products of enzymic hydrolysis followed by intramolecular migrations of acetyl groups are also described.