87648-50-8

Basic information

• Product Name: Benzenamine, N-(ethoxymethyl)-
• CAS NO: 87648-50-8
• Molecular Formula: C9H13NO
• Molecular Weight: 151.208
• Mol File: 87648-50-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(ethoxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(ethoxymethyl)-(87648-50-8)
• EPA Substance Registry System: Benzenamine, N-(ethoxymethyl)-(87648-50-8)

Safety Data

• Hazardous Substances Data: 87648-50-8(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 141-52-6 sodium ethanolate 
• 62-53-3 aniline 
• 64-17-5 ethanol 
• 3188-13-4 ethyl chloromethyl ether 

Relevant articles and documents

Preparation of N,O-Aminals as Synthetic Equivalents of H2C=NAr and (H2C=NHAr)+ ions: Neutral- and Acid-promoted Transformations

A general method for the synthesis of N, O-aminals derived from primary aromatic amines is described.The reactivity of these compounds under neutral and acidic conditions has been studied and the title compounds can be envisaged as general purpose H2C=NAr or (H2C=NAr)+ equivalents.N,O-Aminals have been converted into perhydrotriazines by moderate heating and into bis(4-aminoaryl)methane derivatives or N-benzylarylamines, respectively, when heated in acidid media with pH control.Reduction od N,O-acetals with sodium cyanoborohydride has revealed that the C-O bond is broken exclusively in acidic media.

ETHOXYMETHYL ACETATE AND CHLOROMETHYL ETHERS IN REACTIONS WITH DIALKYL HYDROGEN PHOSPHITES AND AMINES

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