87666-65-7

Basic information

• Product Name: 1-(2,6-diphenylphenyl)-2-phenylbenzene
• Synonyms: 1-(2,6-diphenylphenyl)-2-phenylbenzene
• CAS NO: 87666-65-7
• Molecular Weight: 382.505
• Mol File: 87666-65-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(2,6-diphenylphenyl)-2-phenylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,6-diphenylphenyl)-2-phenylbenzene(87666-65-7)
• EPA Substance Registry System: 1-(2,6-diphenylphenyl)-2-phenylbenzene(87666-65-7)

Safety Data

• Hazardous Substances Data: 87666-65-7(Hazardous Substances Data)

Upstream product

• 100-58-3 phenylmagnesium bromide 
• 178099-14-4 1-<2,6-bis(trifluoromethanesulfonyloxy)phenyl>-2-phenylbenzene 
• 2113-51-1 2-iodobiphenyl 
• 82777-09-1 2′-iodo-1,1′:3′,1″-terphenyl 

Relevant articles and documents

Enantioposition-selective arylation of biaryl ditriflates by palladium- catalyzed asymmetric Grignard cross-coupling

Asymmetric cross-coupling of achiral biaryl ditriflates with aryl Grignard reagents in the presence of 1 equiv of lithium bromide and 5 tool % of palladium complex PdCl2[(S)-alaphos], where alaphos stands for (2- dimethylamino)propyldiphenylphosphine, gave axially chiral monophenylation products with high enantioposition-selectivity. The remaining triflate group in the monophenylation products was substituted with carboxyl and diphenylphosphino groups through palladium-catalyzed carbonylation and diphenylphosphinylation, respectively.