87708-32-5

Basic information

• Product Name: 1,4,7,10-Tetraoxacyclododecane-2-methanol, 4-methylbenzenesulfonate
• CAS NO: 87708-32-5
• Molecular Formula: C16H24O7S
• Molecular Weight: 360.428
• Mol File: 87708-32-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,4,7,10-Tetraoxacyclododecane-2-methanol, 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4,7,10-Tetraoxacyclododecane-2-methanol, 4-methylbenzenesulfonate(87708-32-5)
• EPA Substance Registry System: 1,4,7,10-Tetraoxacyclododecane-2-methanol, 4-methylbenzenesulfonate(87708-32-5)

Safety Data

• Hazardous Substances Data: 87708-32-5(Hazardous Substances Data)

Upstream product

• 75507-26-5 2-(hydroxymethyl)-12-crown-4 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 1373434-01-5 benzyl 4-((1,4,7,10-tetraoxacyciododecan-2-yl)methylthio)-2-methylbutan-2-ylcarbamate 
• 87708-27-8 5-Decyl-2-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxy)-benzoic acid 
• 109953-99-3 [5-Decyl-2-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxy)-phenyl]-phosphonic acid monoethyl ester 
• 126128-17-4 [5-Decyl-2-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxy)-phenyl]-phosphonic acid 
• 144381-58-8 [5-Decyl-2-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxy)-phenyl]-phosphonic acid diethyl ester 
• 87708-35-8 5-Decyl-2-(1,4,7,10-tetraoxa-cyclododec-2-ylmethoxy)-benzoic acid methyl ester 

Relevant articles and documents

Sulfoxides as response elements for fluorescent chemosensors

Sulfoxides are shown to be viable reporting groups for fluorescent chemosensor development. Metal coordination of sulfoxide-appended fluorophores suppresses excited-state pyramidal inversion of the sulfoxide, leading to enhanced fluorescence emission. This new structural motif allows the construction of fluorescent chemosensors that do not require nitrogen coordination as part of the signaling process, that have a range of selectivities and affinities for oxophilic metal ions, and that can function in water.

NOVEL LIPOPHILIC CROWN CARBOXYLIC ACIDS

Four novel ionizable crowns are formed from reactions of methyl 5-(n-decyl)salicylate with tosylates from hydroxymethyl-12-crown-4, -15-crown-5, -18-crown-6 and -21-crown-7 followed by hydrolysis.