87729-61-1

Basic information

• Product Name: Cyclohexanone, 4-(1,1-dimethylethyl)-2-[3-(trimethylsilyl)-2-propenyl]-, trans-
• CAS NO: 87729-61-1
• Molecular Formula: C16H30OSi
• Molecular Weight: 266.499
• Mol File: 87729-61-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 4-(1,1-dimethylethyl)-2-[3-(trimethylsilyl)-2-propenyl]-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 4-(1,1-dimethylethyl)-2-[3-(trimethylsilyl)-2-propenyl]-, trans-(87729-61-1)
• EPA Substance Registry System: Cyclohexanone, 4-(1,1-dimethylethyl)-2-[3-(trimethylsilyl)-2-propenyl]-, trans-(87729-61-1)

Safety Data

• Hazardous Substances Data: 87729-61-1(Hazardous Substances Data)

Upstream product

• 7299-28-7 Tri-n-butyltin trifluoroacetate 
• 86422-21-1 (E)-3-(trimethylsilyl)-2-propenyl acetate 
• 98-53-3 4-tercbutyl-cyclohexanone 

Relevant articles and documents

On the Palladium-Catalyzed Alkylation of Silyl-Substituted Allyl Acetates with Enolates

Treatment of lithium enolates with trialkylstannyl trifluoroacetates permits their use as nucleophiles in allylic alkylations catalyzed by palladium with high regioselectivity and without polyalkylation.Alkylation without concomitant desilylation occurs for 3-acetoxy-1-(trimethylsilyl)-1-propene and n-butyl 2-acetoxy-4-(trimethylsilyl)-3-butenoate under these conditions.The choice of substituents on the tin does affect the rate of the alkylation; trimethyl substitution proceeds substantially faster than tri-n-butyl substitution.