87735-52-2

Basic information

• Product Name: 3-O-<2,3-di-O-benzyl-4-O-(α-L-fucopyranosyl)-α-L-fucopyranosyl>-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose
• CAS NO: 87735-52-2
• Molecular Weight: 732.822
• Mol File: 87735-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-O-<2,3-di-O-benzyl-4-O-(α-L-fucopyranosyl)-α-L-fucopyranosyl>-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-<2,3-di-O-benzyl-4-O-(α-L-fucopyranosyl)-α-L-fucopyranosyl>-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose(87735-52-2)
• EPA Substance Registry System: 3-O-<2,3-di-O-benzyl-4-O-(α-L-fucopyranosyl)-α-L-fucopyranosyl>-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose(87735-52-2)

Safety Data

• Hazardous Substances Data: 87735-52-2(Hazardous Substances Data)

Upstream product

• 16741-27-8 2,3,4-tri-O-acetyl-α-L-fucopyranosyl bromide 
• 87735-47-5 3-O-(2,3-di-O-benzyl-α-L-fucopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 87735-46-4 3-O-(2-O-benzyl-α-L-fucopyranosyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 37813-15-3 2-O-benzyl-3,4-di-O-(p-nitrobenzoyl)-α-L-fucopyranosyl bromide 

Relevant articles and documents

SYNTHESIS OF OLIGOSACCHARIDES OF L-FUCOSE CONTAINING α- AND β-ANOMERIC CONFIGURATIONS IN THE SAME MOLECULE

Some L-fucopyranosyl di-, tri-, and tetra-saccharides containing D-glucose and D-galactose have been synthesised.The use of mercuric cyanide and 2-O-benzyl-3,4-di-O-p-nitrobenzoyl-α-L-fucopyranosyl bromide gave α-L-fucopyranosides stereospecifically, but 2,3,4-tri-O-acetyl-α-L-fucopyranosyl bromide gave mixtures with selectivity favouring the β anomer.A tetrasaccharide was prepared containing both α- and β-L-fucopyranosyl residues in the same molecule, as part of a structure occuring in some extracellular bacterial polysaccharides.The configuration and positions of substitution of fucopyranosyl residues were clearly shown by 1H- and 13C-n.m.r. data.