877593-11-8Relevant articles and documents
Azaindole synthesis through dual activation catalysis with N-heterocyclic carbenes
Sharma, Hayden A.,Todd Hovey,Scheidt, Karl A.
supporting information, p. 9283 - 9286 (2016/07/25)
A convergent, transition-metal-free synthesis of 2-aryl-azaindoles has been developed. The interception of a reactive aza-ortho-azaquinone methide intermediate by an acyl anion equivalent generated through carbene catalysis provides high yields, a wide substrate scope, and the synthesis of previously inaccessible azaindoles.
Preparation and chemical behavior of 2-(tert-butoxycarbonyl)amino-3- bromomethyl pyridine, a novel alkylating agent
Krasavin, Mikhail,Shkavrov, Sergey,Kravchenko, Dmitry
, p. 181 - 186 (2007/10/03)
Synthesis of a novel heterocyclic alkylating agent has been developed. Its instability toward elevated temperatures and/or polar media can be used to prepare 8-aza-1,4-dihydrobenzo[1,3-d]oxazin-2-one. Copyright Taylor & Francis LLC.