87826-74-2Relevant articles and documents
Stereoselective Synthesis of Alcohols, XV. Stereoselective Synthesis of α-Alkyl-α,β-dihydroxycarboxylic Ester Derivatives: Synthesis of (+)-Viridifloric Acid
Ladner, Wolfgang
, p. 3413 - 3426 (2007/10/02)
Reaction of the alkyl 1,3-dioxolan-4-carboxylates 2 with lithium diisopropylamide generated the enolates 3 which on reaction with methyl iodide yielded the products 4 (favoured) and 5.The reaction of the enolate (+)-3e with acetone under thermodynamic con