87876-93-5Relevant articles and documents
Preparative synthesis of cyclohexanone oxime esters
Dikusar,Zhukovskaya
experimental part, p. 1389 - 1391 (2009/09/06)
Preparative procedures have been developed for the synthesis of cyclohexanone oxime esters by acylation of cyclohexanone oxime with carboxylic acid anhydrides in the presence of perchloric acid or with carboxylic acid chlorides in the presence of pyridine
Improved procedures for the Beckmann rearrangement: The reaction of ketoxime carbonates with boron trifluoride etherate
Anilkumar,Chandrasekhar, Sosale
, p. 5427 - 5429 (2007/10/03)
A variety of ketoxime ethyl carbonates-easily prepared from the oximes and ethyl chloroformate-undergo the Beckmann rearrangement upon treatment with 1 equivalent of boron trifluoride etherate, in dichloromethane solution at room temperature in excellent yields (generally 75-99%). (C) 2000 Elsevier Science Ltd.