880344-77-4

Basic information

• Product Name: Benzoic acid (2S,3R)-5-[(1R,3S)-1,3-dimethyl-4-(2-trimethylsilanyl-ethoxycarbonylamino)-butyl]-5-methoxy-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester
• Synonyms: Benzoic acid (2S,3R)-5-[(1R,3S)-1,3-dimethyl-4-(2-trimethylsilanyl-ethoxycarbonylamino)-butyl]-5-methoxy-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester
• CAS NO: 880344-77-4
• Molecular Weight: 577.791
• Mol File: 880344-77-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid (2S,3R)-5-[(1R,3S)-1,3-dimethyl-4-(2-trimethylsilanyl-ethoxycarbonylamino)-butyl]-5-methoxy-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (2S,3R)-5-[(1R,3S)-1,3-dimethyl-4-(2-trimethylsilanyl-ethoxycarbonylamino)-butyl]-5-methoxy-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester(880344-77-4)
• EPA Substance Registry System: Benzoic acid (2S,3R)-5-[(1R,3S)-1,3-dimethyl-4-(2-trimethylsilanyl-ethoxycarbonylamino)-butyl]-5-methoxy-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester(880344-77-4)

Safety Data

• Hazardous Substances Data: 880344-77-4(Hazardous Substances Data)

Upstream product

• 343782-92-3 Benzoic acid (2S,3R)-5-((1R,3S)-4-azido-1,3-dimethyl-butyl)-5-methoxy-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester 
• 80149-80-0 2-(Trimethylsilyl)ethyl 4-nitrophenyl carbonate 

Downstream Products

• 615285-01-3 (2S,3R,5R,8S,10R)-3-Benzoyloxy-8,10-dimethyl-2-((2S,4R)-4-methyl-6-oxo-tetrahydro-pyran-2-yl)-1-oxa-6-aza-spiro[4.5]decane-6-carboxylic acid 2-trimethylsilanyl-ethyl ester 

Relevant articles and documents

Total synthesis of the proposed azaspiracid-1 structure, Part 1: Construction of the enantiomerically pure C1-C20, C21-C27, and C28-C40 fragments

As a build-up to the synthesis of the proposed structure of azaspiracid, both enantiomers of fragments 2, 3, and 4 were synthesized stereoselectively. Piv=pivaloyl, PFP = pentafluorophenyl, Teoc = 2-(trimethylsilyl)ethoxycarbonyl, TES = triethylsilyl.