88048-84-4Relevant articles and documents
A new synthesis of highly active Rh-Co alloy nanoparticles supported on N-doped porous carbon for catalytic C-Se cross-coupling and p -nitrophenol hydrogenation reactions
Annas, Dicky,Lee, Hack-Keun,Hira, Shamim Ahmed,Park, Ji Chan,Park, Kang Hyun
, p. 7959 - 7966 (2021/05/21)
Bimetallic Rh-Co nanoparticles supported on nitrogen-doped porous carbon (Rh-Co/NPC) were synthesized from metal precursors and urea through a simple thermal decomposition/reduction under a nitrogen flow. The Rh-Co/NPC nanocatalyst which contains highly dispersed alloy nanoparticles (~6 nm) showed high catalytic performance as well as good recyclability for the C-Se coupling reaction of diphenyl diselenide and aryl boronic acid and p-nitrophenol reduction.
Palladium-Catalyzed Direct Ortho-C-H Selenylation of Benzaldehydes Using Benzidine as a Transient Directing Group
Qiao, Huihao,Sun, Bing,Yu, Qinqin,Huang, Yi-Yong,Zhou, Yirong,Zhang, Fang-Lin
supporting information, p. 6914 - 6918 (2019/09/30)
Benzidine was found to be a novel transient directing group to enable Pd-catalyzed direct selenylation of inert C(sp2)-H bonds of benzaldehydes. Diverse diarylselenides were readily constructed in high efficiency and satisfactory yields with go
METHOD OF PREPARING CORE-SHELL COPPER NANOPARTICLES IMMOBILIZED ON ACTIVATED CARBON AND METHOD OF PREPARING CHALCOGENIDE COMPOUND USING NANOPARTICLES AS CATALYST
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Paragraph 0056; 0065, (2016/11/14)
Disclosed herein is a method of preparing a Cu/Cu2O core-shell copper nanoparticle catalyst having high catalytic activity from [Cu3(BTC)2] and NaBH4 via a simple chemical reduction method. Also disclosed is a method of preparing a chalcogenide compound by using the nanoparticle catalyst as a heterogeneous catalyst in a cross-coupling reaction between a chalcogenide precursor compound and a boron-containing compound. The disclosed cross-coupling reaction is performed via a simple process, and the disclosed nanoparticle catalyst is compatible with various substrates under mild reaction conditions and exhibits excellent recyclability without a reduction in catalytic activity.