88106-32-5

Basic information

• Product Name: Cyclopropane, (1-bromo-2,2-dimethylpropyl)-
• CAS NO: 88106-32-5
• Molecular Formula: C8H15Br
• Molecular Weight: 191.111
• Mol File: 88106-32-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropane, (1-bromo-2,2-dimethylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropane, (1-bromo-2,2-dimethylpropyl)-(88106-32-5)
• EPA Substance Registry System: Cyclopropane, (1-bromo-2,2-dimethylpropyl)-(88106-32-5)

Safety Data

• Hazardous Substances Data: 88106-32-5(Hazardous Substances Data)

Upstream product

• 24382-76-1 1-Cyclopropyl-2,2-dimethyl-propan-1-ol 

Downstream Products

• 55499-02-0 trans-2,2-dimethyl-3-decene 
• 19550-75-5 trans-2,2-dimethyl-3-heptene 
• 91597-37-4 2-cyclopropyl-3,3-dimethylbutane 
• 19550-75-5 2,2-dimethyl-hept-3-ene 

Relevant articles and documents

Regioselective Route to Sterically Hindered Cyclopropylcarbinyl Halides

Reaction of cyclopropylcarbinyl alcohols 1 with hexachloroacetone and triphenylphosphine resulted in 80 - 90 percent yields of the corresponding cyclopropylcarbinyl chlorides 4 regioselectively, with no trace of the homoallylic chloride 2 or the chlorocyclobutane derivative 6a.Similar reaction of 1 with bromine and triphenylphosphine, in dimethylformamide, gave 65 - 80 percent yields of the cyclopropylcarbinyl bromide 5 with trace amounts of the homoallylic bromide 3 but no detectable bromocyclobutane derivative 6b.These reactions are amenable to the preparation of very sterically hindered cyclopropylcarbonyl halides, heretofore inaccessible, regioselectively and in a facile manner.