88151-05-7Relevant articles and documents
α-METALLATED VINYL CARBANIONOIDS. I. FORMATION OF α-STANNYLVINYL ANIONOIDS FROM 1,1-BIS(TRIMETHYLSTANNYL)ALKENES
Mitchell, T.N.,Amamria, A.
, p. 47 - 56 (2007/10/02)
Hydrostannation of 1-stannyl-1-alkynes leads to the formation of 1,1- and 1,2-distannyl-1-alkenes.The former can undergo lithiation (by alkyllithium in THF) with varying degrees of stereospecificity. 1,1-Dilithio-1-alkenes cannot be prepared by double lit