882882-27-1Relevant articles and documents
Oxidation of gem-borylsilylalkylcoppers to acylsilanes with air
Kondo, Junichi,Shinokubo, Hiroshi,Oshima, Koichiro
, p. 1185 - 1187 (2006)
1-Boryl-1-silylalkylcoppers react with molecular oxygen in the presence of pyridine to afford acylsilanes efficiently. The one-pot process consists of two reactions: alkylation of 1-boryl-1-chloro-silylmethyllithium with Grignard reagents in the presence of copper(I) cyanide and aerobic oxidation of the alkylcopper species. This procedure enables us to access the divergent synthesis of acylsilanes.