88296-01-9

Basic information

• Product Name: 2-Thia-6-azabicyclo[2.2.0]hexan-5-one, 4-methyl-1-phenyl-6-(phenylmethyl)-
• CAS NO: 88296-01-9
• Molecular Formula: C18H17NOS
• Molecular Weight: 295.405
• Mol File: 88296-01-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Thia-6-azabicyclo[2.2.0]hexan-5-one, 4-methyl-1-phenyl-6-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Thia-6-azabicyclo[2.2.0]hexan-5-one, 4-methyl-1-phenyl-6-(phenylmethyl)-(88296-01-9)
• EPA Substance Registry System: 2-Thia-6-azabicyclo[2.2.0]hexan-5-one, 4-methyl-1-phenyl-6-(phenylmethyl)-(88296-01-9)

Safety Data

• Hazardous Substances Data: 88296-01-9(Hazardous Substances Data)

Upstream product

• 88295-96-9 N-benzyl-N-(thiobenzoyl)methacrylamide 

Downstream Products

• 88296-03-1 6-Benzyl-4-methyl-2-oxo-1-phenyl-2λ⁴-thia-6-aza-bicyclo[2.2.0]hexan-5-one 
• 7468-30-6 1-benzyl-3,3-dimethyl-4-phenyl-2-azetidinone 

Relevant articles and documents

Thietane-fused β-Lactams via Photochemical Cycloaddition Reaction of N-(α,β-Unsaturated Carbonyl)thioamides

Photolysis of N-(α,β-unsaturated carbonyl)thioamides gave thietane-fused β-lactams in good yields, whereas some of the thioimides formed thiones via β-hydrogen abstraction of the thiocarbonyl group.Substituents at the α-position to the carbonyl carbon lead to a preference for cyclization over β-hydrogen abstraction.From a sensitisation experiment this reaction was shown to proceed via an n?* triplet excited state.