883857-04-3

Basic information

• Product Name: C₂₆H₃₇O₇P
• Synonyms: C₂₆H₃₇O₇P
• CAS NO: 883857-04-3
• Molecular Weight: 492.549
• Mol File: 883857-04-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₆H₃₇O₇P(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₃₇O₇P(883857-04-3)
• EPA Substance Registry System: C₂₆H₃₇O₇P(883857-04-3)

Safety Data

• Hazardous Substances Data: 883857-04-3(Hazardous Substances Data)

Upstream product

• 6829-76-1 ethylphenylphosphinic acid methyl ester 
• 23397-76-4 1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose 
• 1499-22-5 ethylphenylphosphinic chloride 

Downstream Products

• 883857-09-8 (+)-(R_P)-ethylphenylvinylphosphine oxide 

Relevant articles and documents

Practical synthesis of chiral vinylphosphine oxides by direct nucleophilic substitution. Stereodivergent synthesis of aminophosphine ligands

A practical synthesis of optically pure alkylphenylvinylphosphine oxides is described, utilizing a nucleophilic displacement at phosphorus to install the vinyl moiety. The products were used to prepare classes of P-stereogenic aminophosphine (PN) and aminohydroxyphosphine (PNO) ligands. Stereocontrol can be exerted at various stages of the synthesis, to provide specific combinations of chirality in the final product. The effect of the stereogenic phosphorus and match-mismatch of chiralities of PNO ligands were examined in the asymmetric ruthenium-catalyzed hydrogen transfer reduction of three aryl ketones.