883997-32-8

Basic information

• Product Name: methyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate
• CAS NO: 883997-32-8
• Molecular Weight: 466.714
• Mol File: 883997-32-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate(883997-32-8)
• EPA Substance Registry System: methyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-2,6-dimethyl-7-[(phenoxythiocarbonyl)oxy]-2-octenoate(883997-32-8)

Safety Data

• Hazardous Substances Data: 883997-32-8(Hazardous Substances Data)

Upstream product

• 74243-88-2 (βS,4S)-β,2,3-trimethyl-1,3-dioxolane-4-ethanol 
• 883997-25-9 methyl (2E,6S,7S)-7,8-dihydroxy-2,6-dimethyl-2-octenoate 
• 883997-13-5 ethyl (4S,5S,2E)-5,6-isopropylidene-4-methylhexanoate 
• 883997-14-6 ethyl (4S,5S)-5,6-isopropylidene-4-methylhexanoate 
• 883997-27-1 methyl (2E,6S,7S)-8-tert-butyldimethylsiloxy-7-hydroxy-2,6-dimethyl-2-octenoate 
• 1005-56-7 phenylcarbonochloridothioate 

Downstream Products

• 485-43-8 isoiridomyrmecin 
• 485-43-8 iridomyrmecin 

Relevant articles and documents

Stereocontrolled formation of three contiguous stereogenic centers by free radical cyclization - synthesis of (+)-iridomyrmecin and (-)-iso-iridomyrmecin - formal synthesis of δ-skythantine

A synthesis of (+)-iridomyrmecin (1), a naturally occurring insecticide with antibiotic properties, via free radical cyclization is described. In this key step, three contiguous stereogenic centers are generated with a high level of stereo-control. Wiley-