88410-14-4

Basic information

• Product Name: Benzene, (2-bromo-2-fluoroethenyl)-, (E)-
• CAS NO: 88410-14-4
• Molecular Formula: C8H6BrF
• Molecular Weight: 201.038
• Mol File: 88410-14-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Benzene, (2-bromo-2-fluoroethenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-bromo-2-fluoroethenyl)-, (E)-(88410-14-4)
• EPA Substance Registry System: Benzene, (2-bromo-2-fluoroethenyl)-, (E)-(88410-14-4)

Safety Data

• Hazardous Substances Data: 88410-14-4(Hazardous Substances Data)

Upstream product

• 118559-15-2 (E)-β-bromo-β-fluorostyrene 
• 81962-38-1 dibromofluoromethyltriphenylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 321-33-5 (2R,3S)-2,3-Dibromo-2-fluoro-3-phenyl-propionic acid 
• 20397-61-9 (Z)-2-fluoro-3-phenylacrylic acid 
• 20397-60-8 (E)-2-fluoro-3-phenylprop-2-enoic acid 
• 350-99-2 ethyl (E/Z)-2-fluoro-3-phenylprop-2-enoate 
• 350-90-3 (Z/E)-2-fluoro-3-phenylprop-2-enoic acid 
• 321-33-5 2,3-dibromo-2-fluoro-3-phenylpropanoic acid 
• 353-54-8 tribromofluoromethane 
• 88410-05-3 (Z)-β-bromo-β-fluorostyrene 

Downstream Products

• 671-18-1 (Z)-(1-fluoro-2-phenylethenyl)benzene 
• 130490-15-2 (Z)-1,4-Diphenyl-2-fluoro-1-buten-3-yne 
• 671-19-2 (E)-(1-fluoroethene-1,2-diyl)dibenzene 
• 20405-78-1 (Z)-(2-fluorovinyl)benzene 
• 101560-10-5 (Z)-3-Fluoro-4-phenyl-3-buten-2-one 

Relevant articles and documents

Concise preparation of fluorine-containing carbocycles involving the Diels-Alder reaction using fluorinated alkene or diene derivatives

The Diels-Alder reaction of trifluorovinyl substances with various dienes proceeded well to give the corresponding trifluorinated cyclohexene derivatives in a regiospecific manner, while 2,3-difluorobuta-1,3-diene molecules also underwent a smooth Diels-A

Photochemical generation and structure of vinyl radicals

Photolysis of a series of E or Z stereoisomeric α-R-substituted bromostyrenes (R = CH3, F or CN) in methanol yields E and/ or Z stereoisomeric styrenes, which stem from the corresponding vinyl radicals. The results show that the α-Me vinyl radical is a rapidly equilibrating, bent structure, while the α-F vinyl radical is a stable bent species, in agreement with earlier thermal results. The α-CN vinyl radical is assigned as a rapidly inverting bent and not a linear species from the stereochemical results as a function of temperature. Stereochemical data for the α-C(H)=O system in diethyl ether indicate a stable bent vinyl radical as product forming species. The conclusions are supported by quantum chemical computations. Wiley-VCH Verlag GmbH & Co. KGaA.

Low-temperature 19F NMR spectroscopy of 1-fluoro-1-lithioethenes - Stability, shifts and unexpected coupling constants

Half-lives and fluorine atom shifts of stabilized 1-fluoro-l-lithioethenes bearing hydrogen, fluorine, phenyl, and/or dimethylphenylsilyl groups in the β-positions have been determined by a low-temperature 19F NMR spectroscopy. Some 1-fluoro-1-lithioethenes displayed an exceptionally low value of the trans-3JFF coupling constant. Stereoselectivity of carbenoid formation, as well as an effect of configuration on the stability is discussed.