88476-29-3Relevant articles and documents
Acid-Stable, Solvolytically Deblocked Amino-Protecting-Groups Applications of the 1,3-Dibromo-2-methyl-2-propyloxycarbonyl (DB-t-Boc) Group
Carpino, Louis A.,Rice, Norman W.,Mansour, E. M. E.,Triolo, Salvatore A.
, p. 836 - 842 (2007/10/02)
The effects of structure on the ease of solvolytic deblocking of an array of α-halo-tert-alkyl carbamates 1 have been studied.The corresponding thiolcarbamates were shown to undergo isomerization and other reactions due to participation of the sulfur atom