884842-78-8Relevant articles and documents
Synthesis and crystal structure of tetracoordinated molybdenum (II) complexes containing rigid α-diimine ligands
Turki, Thouraya,Guerfel, Taha,Bouachir, Faouzi
, p. 1142 - 1146 (2008/10/09)
The complex of the general formula (dad)MoCl2 [3ai, 3bi, 3c] (dad = R′NC(R)-C(R)NR′) is obtained in one step by reduction of [MoCl4(thf)2] (1) in the presence of dad ligands (dab: ai, Ar-BIAN: bi, Ph-BIC: c) (2). All new complexes have been characterized by IR and NMR spectroscopy. The X-ray single-crystal diffraction of 3a2 reveals a relatively tetrahedral coordination geometry.