88511-99-3Relevant articles and documents
Direct Synthesis of Organobromogermanes from Methylenebromide
Schmidbaur, Hubert,Rott, Johann
, p. 285 - 287 (2007/10/02)
From the copper-catalyzed reaction of germanium powder with dibromomethane at 310 deg C a mixture of alkylbromogermanes is obtained.The major products are CH3GeBr3, Br3GeCH2Br (1), CH2(GeBr3)2 (2) and (CH2GeBr2)3 (3).The product distribution parallels the analogous reaction with dichloromethane reported previously.All compounds were characterized by analytical and spectroscopic data, and can be converted into the corresponding hydrides. - Keywords: Alkylbromogermanes, Synthesis, CVD Feeding Gas, Germanium/Copper Mixtures
The Reaction of Germanium Atoms with Organic Halides
Mochida, Kunio,Tashiro, Kumiko
, p. 1105 - 1108 (2007/10/02)
Co-condensation of thermally evaporated germanium vapor with organic halides yields a mixture of trihalogermyl derivatives and tetrahalogermanes as major products.The nature of these reactions is discussed.