88548-75-8

Basic information

• Product Name: bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))
• Synonyms: bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))
• CAS NO: 88548-75-8
• Molecular Weight: 1117.66
• Mol File: 88548-75-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))(CAS DataBase Reference)
• NIST Chemistry Reference: bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))(88548-75-8)
• EPA Substance Registry System: bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))(88548-75-8)

Safety Data

• Hazardous Substances Data: 88548-75-8(Hazardous Substances Data)

Upstream product

• 73621-81-5 2(C₆H₅)4P⁽¹⁺⁾*Cl₂WS₂FeS₂FeCl₂^(2-)=((C₆H₅)4P)2[Cl₂WS₂FeS₂FeCl₂] 
• 13862-78-7 ammonium tetrathiotungstate 
• 2001-45-8 tetraphenyl phosphonium chloride 

Downstream Products

• 73621-81-5 2(C₆H₅)4P⁽¹⁺⁾*Cl₂WS₂FeS₂FeCl₂^(2-)=((C₆H₅)4P)2[Cl₂WS₂FeS₂FeCl₂] 

Relevant articles and documents

Synthesis and characterization of the bimetallic series [S 2WS2Fe(NCS)(X)]2- (X = Cl-, NCS -, N3-)

The family of molecular dianions [S2WS2Fe(NCS)(X)]2-(X=Cl-,NCS-,N3-orN3-) has been synthesized and characterized by X-ray diffraction, IR, electronic and electrospray mass spectroscopies. This series of compounds was obtained using the lability of the terminal chloro ligands in [S2WS 2FeCl2]2-. A series of thioheterobimetallic anions have been synthesized: [S2WS2Fe(NCS)X]2- (X = Cl- (1); X = NCS- (2); X=N3- (3)). The molecular dianions were isolated by substitution in [S2WS2FeCl 2]2- of the labile terminal chloro ligands by NCS - and/or N3-. Anions (1) and (3) are the first iron tris-heteroleptic complexes of the well-known [S2WS2FeX2] 2- (M = Mo, W) family. The structures of the three molecular anions, isolated as tetraphenylphosphonium salts, are reported, as well as characterization by IR, electronic and electrospray mass spectroscopies.