88682-86-4

Basic information

• Product Name: trichloro((dimethylamino)phenylcarbene)gold(III)
• CAS NO: 88682-86-4
• Molecular Weight: 436.519
• Mol File: 88682-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trichloro((dimethylamino)phenylcarbene)gold(III)(CAS DataBase Reference)
• NIST Chemistry Reference: trichloro((dimethylamino)phenylcarbene)gold(III)(88682-86-4)
• EPA Substance Registry System: trichloro((dimethylamino)phenylcarbene)gold(III)(88682-86-4)

Safety Data

• Hazardous Substances Data: 88682-86-4(Hazardous Substances Data)

Upstream product

• 30971-68-7 pentacarbonyl[(N,N-dimethylamino)phenylmethylene]chromium⁽⁰⁾ 
• 88667-07-6 pentacarbonyl((dimethylamino)phenylcarbene)molybdenum⁽⁰⁾ 

Downstream Products

• 88727-29-1 tribromo((dimethylamino)phenylcarbene)gold(III) 

Relevant articles and documents

Transition Metal Carbene Complexes, CXXXII. Synthesis of Novel Gold(I)- and Gold(III) Carbene Complexes

Pentacarbonyl complexes of chromium(0) (1a), molybdenum(0) (1b), and tungsten(0) (1c) react with chloroauric acid to give chlorogold(I) (2) and trichlorogold(III) (3), while the reaction of 1c with bromoauric acid yields only bromogold(I) (4).Tribromogold(III) (5) is obtained either from 4 by oxidative addition of bromine or from 3 by halogene substitution with boron tribromide. triiodogold(III) (6) is prepared by further halogene substitution from 5 with boron triiodide; it is reduced with sodium thiosulfate to give iodogold(I) (7).