88691-40-1Relevant articles and documents
NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 37. TRIMETHYLSILYLDIAZOMETHANE. A CONVENIENT REAGENT FOR THE PREPARATION OF VINYLSILANES FROM ALKANESULFONYL CHLORIDES
Aoyama, Toyohiko,Toyama, Sachio,Tamaki, Naoko,Shioiri, Takayuki
, p. 2957 - 2959 (2007/10/02)
Trimethylsilyldiazomethane reacts smoothly with alkanesulfonyl chlorides in the presence of triethylamine to give vinylsilanes.KEYWORDS - trimethylsilyldiazomethane; vinylsilane; alkanesulfonyl chloride; thermal isomerization; sulfene; episulfone