887001-78-7

Basic information

• Product Name: [((Me)BDK)FeCH₂Ph]*THF-d8
• CAS NO: 887001-78-7
• Molecular Weight: 644.681
• Mol File: 887001-78-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [((Me)BDK)FeCH₂Ph]*THF-d8(CAS DataBase Reference)
• NIST Chemistry Reference: [((Me)BDK)FeCH₂Ph]*THF-d8(887001-78-7)
• EPA Substance Registry System: [((Me)BDK)FeCH₂Ph]*THF-d8(887001-78-7)

Safety Data

• Hazardous Substances Data: 887001-78-7(Hazardous Substances Data)

Upstream product

• 1589-82-8 phenylmagnesium bromide 
• 289618-59-3 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene 
• 1693-74-9 tetrahydrofuran-d8 

Relevant articles and documents

Neutral and cationic Fe(II) β-diketiminate complexes

The three-coordinate, 12-valence electron complexes [(MeBDK)FeR] (MeBDK = [HC(C(Me)NAr)2]-, Ar = 2,6-iPr 2C6H3, R = CH2Ph, CH 2SiMe3) are reported as well as their reactivity towards Lewis bases. With perfluoroaryl borane and -borate type activators, the monoalkyls react to give alkyl-free paramagnetic cationic iron species counterbalanced by perfluorinated arylborate anions. The paramagnetic nature of the cations permits the observation of weak and dynamic interactions with these anions via 19F NMR spectroscopy.