88717-96-8

Basic information

• Product Name: Bicyclo[3.2.1]oct-3-en-6-ol, 4,7-dimethyl-, (6-endo,7-exo)-
• CAS NO: 88717-96-8
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Mol File: 88717-96-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[3.2.1]oct-3-en-6-ol, 4,7-dimethyl-, (6-endo,7-exo)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[3.2.1]oct-3-en-6-ol, 4,7-dimethyl-, (6-endo,7-exo)-(88717-96-8)
• EPA Substance Registry System: Bicyclo[3.2.1]oct-3-en-6-ol, 4,7-dimethyl-, (6-endo,7-exo)-(88717-96-8)

Safety Data

• Hazardous Substances Data: 88717-96-8(Hazardous Substances Data)

Upstream product

• 37905-03-6 8-hydroxygeranyl acetate 
• 70238-37-8 (2'Z,6'E)-Essigsaeure-(8'-hydroxy-3',7'-dimethyl-2',6'-octadien-1'-yl)ester 
• 88717-91-3 1-O-methyl-10-hydroxynerol 
• 88717-90-2 1-O-methyl-10-hydroxygeraniol 

Relevant articles and documents

Chemical Tranformation of Terpenoids. V. Acidic Conversions of 10-Hydroxygeraniol and 10-Hydroxynerol Derivatives Leading to Cyclic Monoterpenoids

Acid treatment of 1-O-acetyl-10-hydroxygeraniol (5a), 1-O-methyl-10-hydroxygeraniol (5b), 1-O-acetyl-10-hydroxynerol (6a), and 1-O-methyl-10-hydroxynerol (6b) was investigated under various conditions.It was found that treatment of 5a and 6a with HCOOH gave menth-1-ene-8,9-diol (7), while treatment of 5a, 5b, 6a, or 6b with BF3-etherate in CH2Cl2 furnished two menthofuran-type compounds (9, 10) and two bicyclooct-2-ene derivatives (17, 24).Both 9 and 10 were successfully converted to menthofuran (16) and 17 was converted to a bicyclooctenone derivative (23) which was a key intermediate for a synthesis of juvabione (27).Keywords - geraniol; nerol; 10-hydroxygeraniol; 10-hydroxynerol; 10-hydroxygeraniol derivative; 10-hydroxynerol derivative; uroterpenol; menthofuran; bicyclooct-2-ene derivative